Hi, Zach.
You'll need to clarify a bit what do you mean by "discrimination" here. It seems you are looking for some kind of authorization capabilities. Like, depending on user, it should, or should not respond with success, or may be it should send different set of attributes. Is it what you have in mind? When it comes to SAML, Gluu doesn't offer any easy-to-use authorization options. You need to do all access rights' checks at your SP, based on the response from Gluu.
It's surely possible to configure Shibboleth IdP (which is used by Gluu for SAML-related things internally) to do some kind of authorization, but it will require to edit its config files on disk (no web UI support), and such things are not covered by Community support. You can try Shibboleth docs/forums for details.
Those groups you may see are used mainly with [UMA](https://gluu.org/docs/ce/3.0.2/admin-guide/uma/) flows.
So, in short, if you need Gluu to handle authorization, it's recommended to use UMA (you can use oxd server, our other product, to add UMA capabilities to app you want to protect), or try to reconfigure Shib IdP, if you have to use SAML.